Project Objectives
The main objective of Second Act is to improve understanding of stack
degradation and propose durability improvements for μCHP systems using
PEMFC or DMFC.
The project aims at:
•
Analysing long term lifetime tests data from existing systems to identify
main causes for failure related to system operation and quantify
performance degradation of the stacks, over the long term (at least
10,000 hrs and more than 20,000 hrs for some systems considered)
•
Conducting lifetime tests to investigate degradation at cell and stack
levels and to better understand mechanisms involved. Common
degradation mechanisms in stack components (electrodes mainly) will be
particularly considered to help identifying similar type of improvements on
materials and processes to be implemented for lifetime extension.
•
Developing, applying and validating accelerated stress tests (AST) and
specific tests representative of failures in harsh conditions for the different
Fuel Cell technologies
•
Developing and applying in-situ and ex-situ investigation techniques for
better identification and local resolution of the degradation mechanisms.
Heterogeneities in degradation over the cells surface and across the
stacks will be particularly tackled, with regards to local operation and local
conditions (including fuel composition)
•
Developing new statistical approach and models for better understanding
and description of systems stochastic/deterministic degradation,
reversible/permanent degradation and heterogeneities of degradation in
single cells and stacks.
•
Demonstrating stack lifetime improvements increased tolerance to
applications’ relevant cycling or operating modes (e.g. start/stop or idle),
mainly through stack components modifications (in materials, components
design, manufacturing processes…) for Pure H2, Reformate PEMFC and
DMFC. For the improvements of Membrane Electrodes Assemblies that
will be particularly considered as core components, two routes will be
followed, one on raw materials and manufacturing processes to face
mainly defects and one on structured (nonhomogeneous) electrodes and
GDL to face mainly degradation heterogeneities.
o
Improvements will address particular causes of performance
degradation or sources of stack failure thanks to better
understanding gained with experimental and modelling investigations
o
Improvements will be verified at cell and stack level in existing
designs, following validated AST or specific harsh tests in conditions
representative of the systems considered.
© DLR-TT-ECE 2014
European Project
Second Act
Simulation, Statistics and Experiments Coupled to develop
Optimized and Durable µCHP systems using Accelerated Tests